Repozytorium
Wyszukaj
Kolekcje
Inne
Synthesis, structural and spectroscopic properties of tetra(tetraethylammonium) heptaisothiocyanato uranate(III) and neodymate(III).
Autorzy
Rok wydania
1995
Czasopismo
Journal of Alloys and Compounds
Numer woluminu
225
Strony
338-343
DOI
10.1016/0925-8388(94)07117-9
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The synthesis and characterization of a new uranium(III) compound and its neodymium(III) analogue of the formulas [(C2H5)4N]4U(NCS)7 (I) and [(C2H5)4N]4Nd(NCS)7 (II) are reported. Both compounds are isomorphic and crystallize in the tetragonal system, space group I4/mmm with: , , Z = 4, and , , Z = 4, . The IR, Raman and electronic spectra of the compounds have been recorded in the 30–4000 cm−1 and 4000–30 000 cm−1 spectral ranges, respectively, and are further discussed. The assignments of the IR and Raman frequencies based on theoretical considerations are given
Słowa kluczowe
Uranium(III) complexes, Neodymium(III) complexes, Thiocyanato complexes, Crystal structure, IR spectra, Raman spectra, Electronic spectra
Adres publiczny
https://doi.org/10.1016/0925-8388(94)07117-9
Strona internetowa wydawcy
Podobne publikacje
Synthesis and characterization of strontium pentachlorouranate(III) and dibarium heptachlorouranate(III).
Karbowiak Mirosław, Drożdżyński Janusz
Absorption spectrum analysis of uranium(III) formate.
Karbowiak Mirosław, Drożdżyński Janusz
Crystal structure and absorption spectroscopy of Ln(HF2CCOO)3·3H2O(Ln=Pr,Er) single crystals.
Oczko Grażyna, Starynowicz Przemysław