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Halogenoantimonates(III) and halogenobismuthates(III)-a rich family of ferroelectric crystals.
Autorzy
Rok wydania
2003
Czasopismo
Numer woluminu
295
Strony
3-8
DOI
10.1080/714040617
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
In this paper a variety of architectures of self-assembled halo-coordinated MX6 octahedra in ferroelectric halogenoantimonates(III) and halogenobismuthates(III) is illustrated. The dielectric properties of a new ferroelectric [4-NH2C5H4NH][SbCl4] are presented. The para-ferroelectric phase transitions mechanism (C2/c → Cc) at Tc = 270.5 K is discussed. The phase situation in the [4-NH2C5H4NH][MX4] (where M = Sb, Bi and X = Cl, Br) family is compared.
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