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Structure of 1,2,2,3,3,4,4,5-octamethyl-6,7,8-trioxabicyclo[3.2.1]octane.
Autorzy
Rok wydania
1993
Czasopismo
Acta Crystallographica Section C: Structural Chemistry
Numer woluminu
C49
Strony
400-402
DOI
10.1107/S0108270192010175
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Crystals of the unusually stable secondary symmetric ozonide of the title compound (m.p. 374-376 K) con- tain two crystallographicaUy independent but very similar molecules. The five-membered trioxolane tings have en- velope conformations and the pyran rings have chair con- formations in both molecules, with ether O-atom apices. The seven-membered dioxepine rings have boat confor- mations with the peroxide O atoms and the opposite C atom out of the plane of the other ring atoms.