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Inne
IR cryospectroscopic manifestation of complex formation between methoxyflurane and dimethyl ether in liquid Xe.
Autorzy
Rok wydania
2020
Czasopismo
Numer woluminu
742
Strony
137134/1-137134/5
DOI
10.1016/j.cplett.2020.137134
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The IR spectra of mixtures of methoxyflurane and dimethyl ether are studied with the help of FTIR cryospectroscopy in liquefied Xe. The region of CH3 and CH stretching vibrations is examined taking into account the Fermi resonance effect. Comparative analysis of the experimental data and results of ab initio calculations show that the Cl2CH group of methoxyflurane is involved in complex formation which is stabilized by H-bond between H atom of this group and O atom of dimethyl ether predominantly.
Słowa kluczowe
FTIR cryospectroscopy, Methoxyflurane, Dimethyl eter, Xe, Non-covalent interactions, ab initio calculations
Adres publiczny
http://dx.doi.org/10.1016/j.cplett.2020.137134
Strona internetowa wydawcy
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