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Inne
Carbocyclization approaches to electron-deficient nanographenes and their analogues.
Autorzy
Rok wydania
2018
Czasopismo
Numer woluminu
5
Strony
2395-2414
DOI
10.1039/c8qo00423d
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Recent advances in the chemistry of electron-poor polycyclic aromatic molecules are reviewed with a focus on new structural designs and emerging synthetic methods. We review various classes of building blocks, notably those based on rylene imides, and highlight the application of the most successful C–C bond-forming reactions, e.g., tandem Pd-catalyzed couplings, photocyclizations, and the glyoxylic Perkin condensation. These advances are presented in the context of the electronic properties of the resulting materials, which are of high current interest as n-type organic semiconductors.
Adres publiczny
http://dx.doi.org/10.1039/c8qo00423d