Repozytorium

Novel CoCdFe2O4/Chitosan–PANi ternary nanocomposite for High-Efficiency Lead Removal

Autorzy

Thamer Adnan Abdullah

Alyaa H. Abdalsalam

Ali A. Ati

Rashed T. Rasheed

Sarmad Al-Anssari

Oday I. Abdullah

Mukhtar Ali Hussein

Mais A. Mohammed

Karol Kułacz

Phuoc-Cuong Le

Rok wydania

2026

Czasopismo

Journal of Solid State Chemistry

Numer woluminu

355

Strony

125794/1-125794/10

DOI

10.1016/j.jssc.2025.125794

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

Heavy metal pollution, particularly lead (Pb2+), poses a significant threat to the environment and human health. In this study, it was synthesized and analyzed a unique nanocomposite by preparing cadmium-cobalt in specific ratios with ferrite nanoparticles on a polymer. This resulted in the nanocomposite (Co0·2Cd0·8Fe2O4/PANi–g–Chitosan), which was used to remove lead ions efficiently. The nanocomposite consists of cobalt and cadmium ferrite nanoparticles with a chitosan and polyaniline polymer matrix, which was synthesized chemically. This novel nanocomposite exhibits exceptional removal efficiency, demonstrating remarkable performance. The properties of the nanocomposite were investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and UV–Vis spectroscopy. These tests confirmed the successful fabrication and structural integrity of the nanocomposite. The nanocomposite exhibited high adsorption and purification efficiency, achieving 97.8 % removal of lead ions at pH 5. The adsorption behavior was investigated by studying the reaction kinetics (using a pseudo-second-order reaction model) and analyzing the adsorption curve, providing valuable insights into the reaction mechanisms. Notably, the Taguchi method was employed to optimize the adsorption parameters. This analysis revealed that adsorption time and pH value are significant factors. The optimal conditions were: contact time of 90 min, a pH of 5, and a shaking speed of 200 rpm, based on Taguchi results. The removal of lead ions using this nanocomposite revealed great potential as an effective nanocomposite for purifying water.

Słowa kluczowe

adsorption, Nanocomposite, lead ions, ferrite-PANi, Water treatment

Adres publiczny

http://dx.doi.org/10.1016/j.jssc.2025.125794

Strona internetowa wydawcy

http://www.elsevier.com

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