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Structures of the multireceptor vaulted cyclidene complexes.
Autorzy
Rok wydania
1996
Czasopismo
Numer woluminu
246
Strony
109-118
DOI
10.1016/0020-1693(96)05057-8
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The preparations and structures of three vaulted cyclidene complexes are compared with the two previously reported. All show similar structures with large rigid cavities partly closed off by the piperidine risers, illustrating in particular the attractive effect of van der Waals forces resulting in the incorporation of solvent molecules or [PF6]− ions nesting on the edges of the cavities. However, the detailed geometries vary, according to the nature of the ligand substituents, the metal, the counter-ion and the lattice solvent molecules. These give rise to differing orientations of the capping aromatic rings and the piperidine risers.
Słowa kluczowe
Crystal structure, Multireceptor complexes, Vaulted cyclidene complexes
Adres publiczny
https://doi.org/10.1016/0020-1693(96)05057-8
Strona internetowa wydawcy
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