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Attaching metal-capped sp carbon chains to metal clusters : Synthesis, structure and reactivity of rhenium/triosmium complexes of formula [(η5-C5Me5)Re (N))(PPh3)(CC)nOs3(CO)y(X)z]m+, including carbon geometries more distorted than planar tetracoordinate.

Autorzy

S. B. Falloon

Sławomir Szafert

A. M. Arif

John A. Gladysz

Rok wydania

1998

Czasopismo

Chemistry-A European Journal

Numer woluminu

4

Strony

1033-1042

DOI

10.1002/(SICI)1521-3765(19980615)4:6<1033::AID-CHEM1033>3.0.CO;2-P

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

A variety of fascinating C2, C3, C4, and C6 Re/Os3 complexes can be obtained, starting from thermal reactions of alkynyl complexes [(η5-C5Me5)Re(NO)(PPh3){(C≡C)nH}] and [Os3(CO)10(NCCH3)2], or the C3OMe complex [(η5-C5Me5)Re(NO)(PPh3)(C≡CC(OMe)=Os3(CO)11] alone. Two examples of such complexes are shown; the one on the right features a carbon with a geometry even more distorted than “planar tetracoordinate”.

Adres publiczny

https://doi.org/10.1002/(SICI)1521-3765(19980615)4:6<1033::AID-CHEM1033>3.0.CO;2-P

Strona internetowa wydawcy

onlinelibrary.wiley.com

Podobne publikacje
1999

Appreciably bent sp carbon chains : synthesis, structure and protonation of organometallic 1,3,5-triynes and 1,3,5,7-tetraynes of the formula (η5-C5Me5)Re(NO)(PPh3)((C=C) n- p-C6H4Me).

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2000

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