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A new versatile binuclear seven-coordinate complex of molybdenum(II),[(μ-Cl)2{Mo(μ-Cl)(SnCl3)(CO)3}2]2-.
Autorzy
Rok wydania
2009
Czasopismo
Journal of Organometallic Chemistry
Numer woluminu
694
Strony
4196-4203
DOI
10.1016/j.jorganchem.2009.09.006
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The two new seven-coordinate anionic complexes of molybdenum(II), binuclear [(μ-Cl)2{Mo(μ-Cl)(SnCl3)(CO)3}2]2− and mononuclear [MoCl3(GeCl3)(CO)3]2−, have been synthesized and characterized by single-crystal X-ray diffraction studies. The binuclear complex exhibits a unique mode of reactivity towards norbornene. In a strictly anhydrous atmosphere the binuclear complex effectively initiates the ring-opening metathesis polymerization reaction of norbornene, but in the presence of water norbornene is efficiently transformed to the binorbornyl ether (C7H11)2O.
Słowa kluczowe
Molybdenum(II), Stannyl ligand, Germyl ligand, Heterobimetallic complexes, Ring opening metathesis polymerization, Etherification catalyst
Adres publiczny
https://doi.org/10.1016/j.jorganchem.2009.09.006
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