Repozytorium
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Kolekcje
Inne
The crystal structure and properties of TiCl4{CH(CO2Et)3}] and [Al2Cl6{μ-C2H4(CO2Et)2}].
Autorzy
Rok wydania
1996
Czasopismo
Journal of Organometallic Chemistry
Numer woluminu
526
Strony
329-333
DOI
10.1016/S0022-328X(96)06572-2
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The reactions of TiCl4 with CH(CO2Et)3) and AlCl3 with C2H4(CO2Et)2 in CH2Cl2 gave [TiCl4{CH(CO2Et)3}] (1) and Al2Cl6{μ-C2H4(CO2Et)2}] (2) respectively. The crystal structures of 1 and 2 have been determined by a single crystal X-ray diffraction studies and refined by full-matrix least squares techniques to R1 = 0.0272 and 0.0282 (for 2654 and 1274 unique non-zero reflections) for 1 and 2 respectively. The crystals of 1 belong to the space group C2/c with Z = 8 and a = 17.131(8), b = 10.715(3), and β = 92.97(3)°. The titanium atom in 1 is octahedrally coordinated by four terminal chlorine atoms and two oxygen atoms in cis position from the coordinated triester molecule. Crystals of 2 are monoclinic, space group and β = 116.65(2)°. In the molecular dimeric compound, each aluminium atom is tetrahedrally coordinated by three terminal chlorine atoms and one oxygen atom from the bridging diethyl succinate molecule.
Słowa kluczowe
Olefin polymerization, Crystal structure, Titanium, Aluminium, Ester compounds
Adres publiczny
https://doi.org/10.1016/S0022-328X(96)06572-2
Strona internetowa wydawcy
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