Repozytorium
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Kolekcje
Inne
Crystal structure and magnetic interactions of a new alkoxido and azido bridged 1D copper(II) coordination polymer.
Autorzy
Rok wydania
2021
Czasopismo
Journal of Solid State Chemistry
Numer woluminu
303
Strony
122484/1-122484/10
DOI
10.1016/j.jssc.2021.122484
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
A new 1D azido and alkoxido-bridged Cu(II) coordination polymer, [Cu2(H3L)(μ-H2L)(μ-N3)]n (1), was synthesized from the reaction of H4L, Cu(NO3)2·3H2O and NaN3 in methanol, where H4L is (E)-2-((5-bromo-2-hydroxybenzylidene)amino)-2-(hydroxymethyl)propane-1,3-diol. Compound 1 was characterized by elemental analysis, spectroscopic methods and single-crystal X-ray diffraction. Both spectroscopic and structural studies confirmed the presence of the Schiff base and the azide ligands. Azido and alkoxido bridges connect two Cu(II) ions with different coordination environments. The Schiff base ligand, H4L, shows two coordination modes acting as H3L− and H2L2− to the metal cores. The azido ligands show both end-on and end-to-end bridging modes. The magnetic study performed in the 1.8–300 K range shows an overall ferromagnetic interaction among the copper(II) ions dominated by the coupling through the alkoxido bridge. We have calculated the value of the magnetic coupling constants by means of DFT calculations, and we compared their values with those obtained from the magnetic susceptibility measurements.
Słowa kluczowe
Magnetic interaction, Coordination polimer, Crystal structure, DFT calculation, Copper
Adres publiczny
http://dx.doi.org/10.1016/j.jssc.2021.122484
Strona internetowa wydawcy
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