Repozytorium

Control over catenation in pillared paddlewheel metal-organic framework materials via solvent-assisted linker exchange.

Autorzy

Wojciech Bury

David Fairen-Jimenez

Marianne B. Lalonde

Randall Q. Snurr

Omar K. Farha

Joseph T. Hupp

Rok wydania

2013

Czasopismo

Chemistry of Materials

Numer woluminu

25

Strony

739-744

DOI

10.1021/cm303749m

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

Control over catenation in a pillared paddlewheel metal–organic framework was achieved via solvent-assisted linker exchange. The linker exchange was demonstrated on the noncatenated structure of DO-MOF, by using 4,4′-bipyridine (L4) and 4,4′-azobis(pyridine) (L5) as linkers, leading to noncatenated materials SALEM-3 and SALEM-4. The de novo synthesized analogues of SALEM-3 and SALEM-4 can only be obtained as 2-fold interpenetrated frameworks. The reaction progress of the linker exchange was monitored by NMR spectroscopy, and structure and framework catenation were characterized by powder X-ray diffraction and thermogravimetric methods.

Słowa kluczowe

linker exchange, catenation;, metal organic frameworks, sALE

Adres publiczny

http://dx.doi.org/10.1021/cm303749m

Strona internetowa wydawcy

https://www.acs.org/content/acs/en.html

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