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Water-soluble and stable dinitrogen phosphine complexestrans-[ReCl(N2)(PTA-H)n(PTA)4-n]n+ (n=0–4), the first with 1,3,5-triaza-7-phosphaadamantane.

Autorzy

Piotr Smoleński

Armando J. L. Pombeiro

Rok wydania

2008

Czasopismo

Dalton Transactions

Strony

87-91

DOI

10.1039/B712360D

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

The first dinitrogen complexes with the hydrosoluble PTA ligand, or its protonated form PTA-H, trans-[ReCl(N2)(PTA-H)n(PTA)4−n]n+ (n = 0–4), are prepared, shown to be soluble and stable in water, interconvertible by stepwise protonation/deprotonation and to form, upon N2 loss, the corresponding penta-coordinate compounds. Dinitrogen displacement by CO affords trans-[ReCl(CO)(PTA)4].

Adres publiczny

https://doi.org/10.1039/B712360D

Strona internetowa wydawcy

https://www.rsc.org/

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