Repozytorium

Sodium hypodiphosphate – a new ionic conductor. Synthesis, stability, conductivity and 3D electron diffraction crystal structure

Autorzy

Vasyl Kinzhybalo

Jakub Wojciechowski

Przemysław Szklarz

Anna Piecha-Bisiorek

Marta Otręba

Miłosz Siczek

Katarzyna Ślepokura

Rok wydania

2024

Czasopismo

Journal of Materials Chemistry C

Numer woluminu

12

Strony

11347-11351

DOI

10.1039/d4tc01216j

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

Phosphate-based materials are of great interest in the design of solid electrolytes for sodium ion batteries. The synthesis, crystal structure and ionic conductivity of tetrasodium hypodiphosphate are reported. The nanocrystalline anhydrous material, Na4(P2O6), was obtained by dehydration and its crystal structure was determined with 3D electron and X-ray powder diffraction. The effect of chemical modification on the structure and conductivity of the title compound in comparison with its analogues is revealed.

Adres publiczny

http://dx.doi.org/10.1039/d4tc01216j

Strona internetowa wydawcy

https://www.rsc.org/