Repozytorium
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Kolekcje
Inne
Supramolecular stores of acetic acid–an alternative for metal-organic frameworks.
Autorzy
Rok wydania
2009
Czasopismo
Journal of Hazardous Materials
Numer woluminu
169
Strony
1040-1044
DOI
10.1016/j.jhazmat.2009.04.041
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
A series of new complexes: [M(quin-2-c)2(H2O)2]·4CH3COOH (M = Mn2+, Co2+ or Ni2+, quin-2-c is quinoline-2-carboxylate ion) have been synthesized and characterized by X-ray single crystal study. The crystals of the complexes reveal very interesting 1D structures comprising acetic acid molecules. The processes of re- and desolvation of acetic acid by the manganese complex in mild conditions have been studied. The de- and resolvated materials were characterized by elemental analysis, IR spectroscopy and XRD study. The results show that binding of acetic acid is reversible and stoichiometric.
Słowa kluczowe
Acetic acid, Supramolecular network, X-ray study, Quinoline-2-carboxylate ligand
Adres publiczny
https://doi.org/10.1016/j.jhazmat.2009.04.041
Strona internetowa wydawcy
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