Repozytorium

Brucine and two solvates.

Autorzy

Agata Białońska

Zbigniew Ciunik

Rok wydania

2004

Czasopismo

Acta Crystallographica Section C: Structural Chemistry

Numer woluminu

C60

Strony

853-855

DOI

10.1107/S0108270104024874

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

The crystal structures of brucine (2,3-dimethoxystrychnidin-10-one), C(23)H(26)N(2)O(4), brucine acetone solvate, C(23)H(26)N(2)O(4).C(3)H(6)O, and brucine 2-propanol solvate dihydrate, C(23)H(26)N(2)O(4).C(3)H(7)O.2H(2)O, have been determined. Crystals of brucine and its 2-propanol solvate dihydrate exhibit similar monolayer sheet packing, whereas crystals of the acetone solvate adopt a different mode of packing, as brucine pillars. The solvent appears to control the brucine self-assembly on the basis of common donor-acceptor properties of the surfaces.

Adres publiczny

https://doi.org/10.1107/S0108270104024874

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