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Inne
Influence of structural elements on iron(III) chelating properties in a new series of amino acid-derived monohydroxamates.
Autorzy
Rok wydania
2018
Czasopismo
Numer woluminu
473
Strony
286-296
DOI
10.1016/j.ica.2017.06.020
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
A series of amino acid-derived monohydroxamate compounds A1–A7 was synthesized and characterized for their coordination properties of Fe(III). The series varies in their skeletal lengths and compositions; some compounds lack external substituents, others are substituted with external functional amino or carboxylic groups, or alternatively inert methyl. Undertaken investigations allowed the determination of stoichiometry, stability constants and spectroscopic parameters of formed ferric complexes. Incorporation of an external functional group with a dissociable proton affects the coordination behavior; the presence of carboxylic or amino groups hampers the formation of mono-, di- and trihydroxamate ferric complexes of presented compounds. The differences in Fe(III) affinity of the monohydroxamates vs trihydroxamates was reflected by the stability constants and pFe, indicating the superior stability of hexadentate complexes.
Słowa kluczowe
Siderophores, Hydroxamates, Fe(III) complexes
Adres publiczny
http://dx.doi.org/10.1016/j.ica.2017.06.020
Strona internetowa wydawcy
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