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Inne
Plenates: Anion‐Dependent Self‐Assembly of the Pyrrole Cage Encapsulating Silver(I) Clusters
Autorzy
Rok wydania
2023
Czasopismo
Numer woluminu
29
Strony
e202203850/1-e202203850/7
DOI
10.1002/chem.202203850
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The self-assembly of 2,5-diformylpyrrole, tris(2-aminoethyl)amine, and silver(I) yielded, depending on the size and basicity of the anion, new cascade complexes or plenates, i.e., cryptates incorporating Agnn+ clusters. The nature of the product was counterion-dependent, and its formation was either driven by the cascade anion binding or by the argentophilic interactions stabilizing the cluster within the cavity. The reaction of plenates with tetrabutylammonium halides resulted in the protonation-coupled replacement of the Ag33+ with anion(s), yielding cascade cryptates.
Słowa kluczowe
supramolecular chemistry, self-assembly, cage compounds, cryptands, silver
Adres publiczny
http://dx.doi.org/10.1002/chem.202203850
Strona internetowa wydawcy
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