Repozytorium

Isomorphous brucinium 4-nitro-benzoate methanol solvate and brucinium 4-nitrobenzoate dihydrate.

Autorzy

Agata Białońska

Zbigniew Ciunik

Rok wydania

2007

Czasopismo

Acta Crystallographica Section C: Structural Chemistry

Numer woluminu

C63

Strony

o120-o122

DOI

10.1107/S010827010605517X

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

In isomorphous crystals of brucinium 4-nitro­benzoate methanol solvate, C23H27N2O4+·C7H4NO4-·CH3OH, and brucinium 4-nitro­benzoate dihydrate, C23H27N2O4+·C7H4NO4-·2H2O, the brucinium cations form reverse corrugated layers, in which the amine N and amide O atoms of the brucinium cations are located in the grooves and at convex points of the layer surface, respectively. Similarly, as observed for the commonly occurring corrugated brucinium layers, the amide O atoms of the cations are involved in hydrogen bonds in which solvent mol­ecules are the donors.

Adres publiczny

https://doi.org/10.1107/S010827010605517X