Repozytorium
Wyszukaj
Kolekcje
Inne
Isomorphous brucinium 4-nitro-benzoate methanol solvate and brucinium 4-nitrobenzoate dihydrate.
Autorzy
Rok wydania
2007
Czasopismo
Acta Crystallographica Section C: Structural Chemistry
Numer woluminu
C63
Strony
o120-o122
DOI
10.1107/S010827010605517X
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
In isomorphous crystals of brucinium 4-nitrobenzoate methanol solvate, C23H27N2O4+·C7H4NO4-·CH3OH, and brucinium 4-nitrobenzoate dihydrate, C23H27N2O4+·C7H4NO4-·2H2O, the brucinium cations form reverse corrugated layers, in which the amine N and amide O atoms of the brucinium cations are located in the grooves and at convex points of the layer surface, respectively. Similarly, as observed for the commonly occurring corrugated brucinium layers, the amide O atoms of the cations are involved in hydrogen bonds in which solvent molecules are the donors.