Repozytorium
Wyszukaj
Kolekcje
Inne
The crystal structure of tetrachlorobis(triphenlphosphine oxide)tin(IV).
Autorzy
Rok wydania
2001
Czasopismo
Numer woluminu
24
Strony
821-822
DOI
10.1515/MGMC.2001.24.11.821
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The solid state structure of [SnCI4(OPPh3)2] (1) was determined by the X-ray diffraction method. The results indicate that the complex has a distorted octahedral geometry with the two OPPh3 ligands cis to each other: Sn-0 = 2.086(2) A and Sn-Cl = 2.385(1) and 2.395(1) A. The tin atoms lie on a two-fold axis. The compound crystallizes in the monoclinic space group C2/c, with unit cell dimensions a = 13.881(3) A, b = 12.897(3) A. c = 19.492(4) A and β = 95.89(3)° for Ζ = 4. The results are discussed in relationship to the 1R and NMR data.
Adres publiczny
Podobne publikacje
1995
Photochemical reaction of W(CO)6 with SnCL4. II. Synthesis and X-ray structure of tetrachlorobis(triphenylphosphine oxide)tungsten(IV), [WCl4(OPPh3)2].
Szymańska-Buzar Teresa, Głowiak Tadeusz
1989
The crystal structure and properties of di-μ-m-diethylphthalateoctachlorodititanium(IV).
Utko Józef, Sobota Piotr, Lis Tadeusz
1989
The crystal structure of di-μ-chlorobis[trichloro(ethyl acetate)]dizirconium(IV).
Sobota Piotr, Mustafa M. O., Lis Tadeusz