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Advances and property investigations of an organic–inorganic ferroelectric: (diisopropylammonium)2[CdBr4]
Autorzy
Rok wydania
2020
Czasopismo
Numer woluminu
59
Strony
11986-11994
DOI
10.1021/acs.inorgchem.0c00830
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The preparation of materials featuring more than one ferroelectric phase represents a promising strategy for controlling electrical properties arising from spontaneous polarization, since it offers an added advantage of temperature-dependent toggling between two different ferroelectric states. Here, we report on the discovery of a unique ferroelectric–ferroelectric transition in diisopropylammonium tetrabromocadmate (DPAC, (C6H16N)2[CdBr4]) with a Tc value of 244 K, which is continuous in nature. Both phases crystallize in the same polar orthorhombic space group, Iab2. The temperature-resolved second-harmonic-generation (SHG) measurements using 800 nm femtosecond laser pulses attest to the polar structure of DPAC on either side of the phase transition (PT). The dc conductivity parameters were estimated in both solid phases. The anionic substructure is in the form of [CdBr4]2– discrete complexes (0D), while in the voids of the structure, the diisopropylammonium cations are embedded. The ferroelectric properties of phases I and II have been confirmed by the reversible pyroelectric effect as well as by P–E loop investigations. On the basis of the dielectric responses, the molecular mechanism of the PT at 244 K has been postulated to be of mixed type with an indication of its displacive nature.
Słowa kluczowe
Crystal structure, Insulators, Phase transitions, Cations, Polarization
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Pełny tekst licencji: https://creativecommons.org/licenses/by/3.0/pl/legalcode
Adres publiczny
http://dx.doi.org/10.1021/acs.inorgchem.0c00830
Strona internetowa wydawcy
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