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Solvation of alcohols in n-heptane and n-propanol from the acoustic Passynski method.
Autorzy
Rok wydania
2008
Czasopismo
Numer woluminu
114
Strony
109-113
DOI
10.12693/APhysPolA.114.A-109
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The method of Passynski of calculating the solvation numbers from compressibility was applied to solutions of short-chained normal alcohols in n-heptane and n-propanol. The dependences of solvation numbers on length of the solute molecules are surprisingly similar for both solvents. Applicability of the acoustic method for determining the solvation numbers in nonaquous systems, as well as for investigation of intermolecular interactions in them was proved. Some structural similarity of associated alcohol and hydrocarbon in liquid state is suggested.
Adres publiczny
https://doi.org/10.12693/APhysPolA.114.A-109
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