Repozytorium

Stable hemiaminals containing a triazole ring.

Autorzy

Maciej Barys

Zbigniew Ciunik

Krzysztof Drabent

Anna Kwiecień

Rok wydania

2010

Czasopismo

New Journal of Chemistry

Numer woluminu

34

Strony

2605-2611

DOI

10.1039/C0NJ00346H

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

Reactions between 4-amino-1,2,4-triazole and nitro-substituted benzaldehydes in acetonitrile under neutral conditions afford stable hemiaminals, seven of which have been structurally and spectroscopically characterized. Two Schiff bases have also been obtained after the addition of hydrochloric acid to the reaction mixture. We describe a correlation between the conformation and configuration of the hemiaminals, and conclude that the formation of these species is determined by the substituents on the phenyl ring, as well as by the presence of 4-amino-1,2,4-triazole.

Adres publiczny

https://doi.org/ 10.1039/C0NJ00346H

Strona internetowa wydawcy

https://www.rsc.org/

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