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Inne
Trapping of AlMe3 with the oxygen atom of the Zr3(μ3-O) unit.
Autorzy
Rok wydania
2002
Czasopismo
Numer woluminu
21
Strony
3497-3499
DOI
10.1021/om020258t
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
We report for the first time the direct complexation of AlMe3 by a Zr3(μ3-O) core. The precursor [Zr4(μ4-O)(μ-OMe)6Cl8(thf)4] (1) was obtained in the direct reaction of ZrCl4 with methanol. When 1 was allowed to react with AlMe3, [Zr3Al(μ4-O)(μ-OMe)6Cl6(Me)(thf)3] (2) was isolated. An analogous trend was observed in the compound [Zr4Al2(μ4-O)2(OEt)12Cl6] (3), which was obtained in the direct reaction of ZrCl4 with Zr(OEt)4 and Al in thf/EtOH.
Słowa kluczowe
Group theory, Alcohols, Precursors, Catalysts, Oxygen
Adres publiczny
https://doi.org/10.1021/om020258t
Strona internetowa wydawcy
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