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Acyl fluorides as direct precursors to fluoride ketyl radicals: reductive deuteration using SmI2 and D2O.
Autorzy
Rok wydania
2021
Czasopismo
Numer woluminu
57
Strony
5195-5198
DOI
10.1039/d1cc01381e
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
A highly chemoselective reductive deuteration of acyl fluorides to provide α,α-dideuterio alcohols with exquisite levels of deuterium incorporation was developed using SmI2 and D2O as the deuterium source. This method introduces acyl fluorides as attractive radical precursors for the generation of reactive acyl-type fluoride ketyls that should find widespread application in many synthetic strategies involving single electron transfer processes.
Adres publiczny
http://dx.doi.org/10.1039/d1cc01381e
Strona internetowa wydawcy
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