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Inne
Oxozinc carboxylates : a predesigned platform for modelling prototypical Zn-MOFs' reactivity toward water and donor solvents.
Autorzy
Rok wydania
2012
Czasopismo
Numer woluminu
48
Strony
7362-7364
DOI
10.1039/C2CC33094F
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Two unique adducts of an oxozinc carboxylate cluster with H2O and THF were isolated and structurally characterized, [Zn4(μ4-O)(O2CR)6(H2O)(THF)]·2(THF) and [Zn4(μ4-O)(O2CR′)6(THF)3] (where R = benzoate and R′ = 9-antracenecarboxylate anion). The study shows that the zinc centers of the Zn4O core can easily form unique coordination environments without breaking of the Zn–Ocarboxylate bonds.
Adres publiczny
http://dx.doi.org/10.1039/C2CC33094F