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Inne
First imidazole-fused carbaporphyrinoid and its conversion to a N-heterocyclic carbene precursor.
Autorzy
Rok wydania
2020
Czasopismo
Numer woluminu
56
Strony
4836-4839
DOI
10.1039/d0cc01013h
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
A series of novel imidazole-fused carbaporphyrinoids were obtained by a surprisingly simple approach by exploiting the reaction of tosylmethylisocyanide (TOSMIC) with readily obtainable 2-aza-21-carbaporphyrins. A facile methylation of silver(III) complexes of these fused systems leads to cationic N-heterocyclic carbene precursors.
Adres publiczny
http://dx.doi.org/10.1039/d0cc01013h