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Spectroscopic properties of praseodymium perchlorates in alcohols and 2-halogeno derivatives of ethanol. Part III.
Autorzy
Rok wydania
1995
Czasopismo
Journal of Applied Spectroscopy
Numer woluminu
62
Strony
725-730
DOI
10.1007/BF02606522
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Recently we reported the results of spectroscopic investigations of lanthanide anhydrous and hydrated perchlorates in nonaqueous solvents. The main goal was explanation of electron-relaxation processes in the systems studied as well as the mechanism of hypersensitive-transition intensity variations.The intensity variations were discussed within the framework of Mason's polarizability mechanism 13, 4 1.The applicability of the ligand-polarizability mechanism is excellent for 2-halogeno derivatives of ethyl alcohol, but it fails for its 2-fluoro-, bromo-, and iododerivatives.In this paper an effort was made to examine Mason's polarizability mechanism for praseodymium systems.
Adres publiczny
https://doi.org/10.1007/BF02606522
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