Repozytorium
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Kolekcje
Inne
Application of 2-ethylpyrrole for a direct synthesis of 3-substituted inverted porphyrins.
Autorzy
Rok wydania
2001
Czasopismo
Numer woluminu
42
Strony
6389-6392
DOI
10.1016/S0040-4039(01)01259-X
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
3-Ethyl-5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin is the major macrocyclic product in the condensation of 2-ethylpyrrole, pyrrole, and benzaldehyde. Oxidation of the ethyl substituent leads to 3-(1′-hydroxyethyl)- and 3-acetyl-substituted inverted porphyrins.Stochastic, Rothemund-type condensation of pyrrole, 2-ethylpyrrole and an arylaldehyde leads to a 3-ethyl-substituted inverted porphyrin that is readily convertible to 3-(1′-hydroxyethyl)- and 3-acetyl-inverted porphyrins.
Adres publiczny
https://doi.org/10.1016/S0040-4039(01)01259-X
Strona internetowa wydawcy
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