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New porous crystals of Cu(I) complexes with Schiff-base-containing triazole ligands.
Autorzy
Rok wydania
2004
Czasopismo
Inorganic Chemistry Communications
Numer woluminu
7
Strony
224-227
DOI
10.1016/j.inoche.2003.11.008
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The new route of syntheses, crystal structure and properties of two new copper(I) complexes, (CuL 1 2 ) 2 (BF 4 ) 2 .0.5THF (1) and (CuL 2 2 ) 2 (BF 4 ) 2 (2) where L 1 =N-[(E)-(4-chlorophenyl)methylidene]-4H-1,2,4-triazol-4-amine and L 2 =N-[(E)-(3,5-dimethoxyphenyl)methylidene]-4H-1,2,4-triazol-4-amine are described. The planar dimeric molecules of 1 and 2 have a great ability toward building the porous structures of the crystals. The size of formed channels depends on the type of substituents on phenyl group of ligands.
Adres publiczny
https://doi.org/ 10.1016/j.inoche.2003.11.008
Strona internetowa wydawcy
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