Repozytorium
Wyszukaj
Kolekcje
Inne
Electrospray tandem mass spectrometry of poly(3-hydroxybutanoic acid) end groups analysis and fragmentation mechanism.
Autorzy
Rok wydania
1998
Czasopismo
Rapid Communications in Mass Spectrometry
Numer woluminu
12
Strony
357-360
DOI
10.1002/(SICI)1097-0231(19980415)12:7<357::AID-RCM172>3.0.CO;2-C
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The electrospray ionization tandem mass spectrometry technique applied for the first time to aliphatic polyester analysis, allowed fast and reliable identification of the various macromolecules of poly(3-hydroxybutanoic acid) (PHB), synthesized via ring-opening polymerization of β-butyrolactone. It was demonstrated that the biomimetic polymers studied contain various end groups, depending on the anionic initiator employed, and show close similarity to the natural PHB produced by enzymes in living cells of prokaryotic and eukaryotic organisms.
Adres publiczny
https://doi.org/10.1002/(SICI)1097-0231(19980415)12:7<357::AID-RCM172>3.0.CO;2-C