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Inne
New complexes of 6,6''-dimethyl-2,2':6',2''-terpyridine with Ni(II) ions: synthesis, structure and magnetic properties.
Autorzy
Rok wydania
2014
Czasopismo
Numer woluminu
77
Strony
17-23
DOI
10.1016/j.poly.2014.03.058
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Complexation of 6,6″-dimethyl-2,2′:6′,2″-terpyridine ligand (L) with Ni(II) as metal centre resulted in formation of new coordination compounds of the following molecular formula: [NiLCl2] (1), [NiL(NO3)2] (2) and [NiL(H2O)3](ClO4)2·2H2O (3). X-ray crystallographic analysis revealed that synthesized complexes are monomeric, with coordination number and geometry varying in dependence to the applied counterion. Metallo-molecular systems were characterized by elementary analysis, spectral techniques (FT-IR, ESI-MS) and evaluated in terms of their magnetic properties.
Słowa kluczowe
Terpyridine, Nickel(II) complexes, Magnetic properties, Crystal structures, Self-assembly
Adres publiczny
http://dx.doi.org/10.1016/j.poly.2014.03.058
Strona internetowa wydawcy
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