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Extension of antiaromatic norcorrole by cycloaddition.
Autorzy
Rok wydania
2018
Czasopismo
Numer woluminu
54
Strony
2510-2513
DOI
10.1039/c8cc00447a
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The antiaromatic ring of norcorrole, a contracted tetrapyrrolic porphyrinoid, was subjected to [2+3] dipolar cycloaddition of iminonitriles. The paratropic character of the resulting chiral chlorines was retained. The chlorins were easily dehydrogenated in the presence of air, yielding pyrazole-fused norcorroles with markedly enhanced paratropicity.
Adres publiczny
http://dx.doi.org/10.1039/c8cc00447a
Strona internetowa wydawcy
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