Repozytorium

Studies of reorganization of the molecules during smectic A-smectic C phase transition using infrared spectroscopy and generalized two-dimensional correlation analysis.

Autorzy

Natalia Osiecka

Zbigniew Galewski

Ewa Juszyńska-Gałązka

Maria Massalska-Arodź

Rok wydania

2016

Czasopismo

Journal of Molecular Liquids

Numer woluminu

224

Strony

677-683

DOI

10.1016/j.molliq.2016.10.080

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

The FT-IR spectra of the 4-hexyloxybenzylidene-4′-dodecyloxyaniline (6BA12) were studied as a function of temperature to describe reorganization of spatial distribution of molecules during various liquid crystal phase transitions: isotopic liquid (IL) – nematic (N), nematic – smectic A (SmA), smectic A – smectic C (SmC), smectic C – smectic I (SmI). The main focus is on the SmA-SmC and SmC-SmI transitions. Two dimensional correlation analysis (2D-IR) of IR spectra has been used to check changes of the arrangement and specific interactions of molecules during phase transitions. A moving-window autocorrelation analysis has been applied to locate transition points basing on the spectroscopic data.

Słowa kluczowe

2DIR, Smectic C, Moving-window autocorrelation analysis, schiff base, iR spectroscopy, liquid crystals, Smectic A

Adres publiczny

http://dx.doi.org/10.1016/j.molliq.2016.10.080

Strona internetowa wydawcy

http://www.elsevier.com

Podobne publikacje
2023

Distinguishing the Focal-Conic Fan Texture of Smectic A from the Focal-Conic Fan Texture of Smectic B

Osiecka-Drewniak Natalia, Galewski Zbigniew, Juszyńska-Gałązka Ewa