Repozytorium

Crystal structure of 2-[benzyl-(7-oxo-cyclohepta-1,3,5-trienyl)-amino]-Ncyclohexylpropanamide.

Autorzy

Ali Ramazani

Sang Woo Joo

Issa Amini

Katarzyna Ślepokura

Tadeusz Lis

Ali Souldozi

Rok wydania

2015

Czasopismo

Journal of Structural Chemistry

Numer woluminu

56

Strony

468-471

DOI

10.1134/S0022476615030105

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

The title compound 2-[benzyl-(7-oxo-cyclohepta-1,3,5-trienyl)-amino]-N-cyclohexylpropanemide is synthesized and studied by the single crystal X-ray diffraction method. The structure of the product was confirmed by IR, 1H and 13C NMR spectroscopy, and mass spectrometry. The tropone oxygen atom plays an important role in the solid-state molecular structure stabilization by being involved in intramolecular N-H⋯O and C-H⋯O contacts.

Słowa kluczowe

single crystal X-ray structure, Smiles rearrangement, Ugi-type coupling, tropolone cyclohexylisocyanide, benzyl amine, acetaldehyde, Ugi-Smiles-type reaction

Adres publiczny

http://dx.doi.org/10.1134/S0022476615030105

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