Wydział Chemii

Fatemeh Ajormal

Rahman Bikas

Nader Noshiranzadeh

Anna Kozakiewicz-Piekarz

Tadeusz Lis

2022

New Journal of Chemistry

46

19468-19481

10.1039/d2nj03826a

Naukowa

Angielski

Artykuł

Three Cu(II) coordination compounds, [Cu(L¹)(Cl₂)] (1), [Cu(L¹)(Br₂)] (2), and [Cu(L²)(Cl)]Cl·(C₂H₄O₃)_0.5(H₂O)_0.5 (3), were synthesized and characterized by various spectroscopic methods and single crystal X-ray analysis where L¹ and L² are oxazolo[3,4-c]oxazole ligands containing a pyridine ring. These compounds were synthesized by two methods including the reaction of copper salt with a pre-synthesized ligand and also the reaction of copper salt with raw materials for the synthesis of the ligands. The results indicated that Cu(II) ions have a catalytic effect on the formation of oxazolo[3,4-c]oxazole ligands. The resulting coordination compounds were used as catalysts for the green synthesis of symmetric and non-symmetric 1,2,3-triazoles by an azide–phenylacetylene–epichlorohydrin cycloaddition reaction. The catalytic reactions were performed in water as a green solvent and the effects of some parameters like the ratio of the reagents, the temperature of the reaction, and also the structure of catalysts were investigated. The results showed that an epoxide ring has higher activity than alkyl chloride functionality for the in situ production of organic azides. Also, it was found that both symmetric and non-symmetric 1,2,3-triazoles can be synthesized by controlling the reaction conditions under mild and green conditions.

http://dx.doi.org/10.1039/d2nj03826a

https://www.rsc.org/