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Enhanced gas sorption properties and unique behavior toward liquid water in a pillared-paddlewheel metal–organic framework transmetalated with Ni(II).
Autorzy
Rok wydania
2014
Czasopismo
Numer woluminu
53
Strony
10432-10436
DOI
10.1021/ic501467w
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The synthesis of a permanently porous pillared-paddlewheel metal–organic framework (MOF) was achieved through transmetalation of Zn(II) with Ni(II). The MOF can be treated with liquid water, leading to the reversible displacement of 50% of its pillars by water molecules and resulting in a most unusual crystalline and permanently porous structure.
Adres publiczny
http://dx.doi.org/10.1021/ic501467w