Repozytorium

Effect of electrical and mechanical anharmonicity on vibrational spectra of H-bonded complexes: phenol···B (B=acetonitrile, pyridine) systems.

Autorzy

S. M. Melikova

D. Shchepkin

Aleksander Koll

Rok wydania

1998

Czasopismo

Journal of Molecular Structure

Numer woluminu

448

Strony

239-246

DOI

10.1016/S0022-2860(98)00355-X

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

The model of the anharmonic dipole moment function of the H-bonded complex AH.-.B is applied to C6HsOH(D) complexes with acetonitrile and pyridine. The frequencies and absolute intensities data for the overtones and the fundamental absorption bands in a wide spectral region (8000-50 cm <) and derivatives of the dipole moment function are presented and compared with ab initio calculation results on the Dk-T B3LYP/6-31G** level.

Słowa kluczowe

Hydrogen bond, Anharmonicity, Dipole moment function, Vibrational spectra Phenol

Adres publiczny

https://doi.org/10.1016/S0022-2860(98)00355-X

Strona internetowa wydawcy

http://www.elsevier.com

Podobne publikacje
2008

Charge density analysis of two proton transfer complexes : understanding hydrogen bonding and determination of in-crystal dipole moments.

Thomas R., Pal S., Datta A., Marchewka Mariusz K., Ratajczak Henryk, Pati S. K., Kulkarni G. U.

2002

FT-IR studies of CH...B interactions in fluoroform containing cryosolutions.

Melikova S. M., Rutkowski K. S., Rodziewicz Paweł, Koll Aleksander