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Bowls, hoops, and saddles : synthetic approaches to curved aromatic molecules.
Autorzy
Rok wydania
2019
Czasopismo
Angewandte Chemie - International Edition
Numer woluminu
58
Strony
86-116
DOI
10.1002/anie.201807004
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
This review summarizes recent advances in the chemistry of curved aromatic molecules. By focusing on the key accomplishments of the last decade, we provide a general overview of synthetic methods capable of efficient induction of internal strain in π-conjugated frameworks. The review is structured according to the topology change involved in the strain-inducing reaction step (cyclizations, eliminations, ring expansions and contractions), and highlights the striking diversity of structures achievable with modern synthetic methodology.
Słowa kluczowe
C−C coupling, fused-ring systems, macrocycles, strained molecules, synthetic methods
Adres publiczny
http://doi.org/10.1002/anie.201807004
Strona internetowa wydawcy
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