Repozytorium

Chelating effect in 4(5)-hydroxymethyl-5(4)-methylimidazole complexes.

Autorzy

K. Kurdziel

Tadeusz Głowiak

Julia Jezierska

Rok wydania

2003

Czasopismo

Inorganic Chemistry Communications

Numer woluminu

6

Strony

459-461

DOI

10.1016/S1387-7003(03)00010-8

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

Light pink crystal of composition [Co(4-CH2OH-5-CH3im)4](NO3)2 (where 4-CH2OH-5-CH3im denotes 4-hydroxymethyl-5-methylimidazole) were obtained from 2-propanol. The complex has been characterized by single-crystal X-ray as well as by electronic and vibrational spectroscopy. The immediate surrounding of the central ion is made up of four nitrogen atoms of the heterocyclic rings and two oxygen atoms of the hydroxymethyl group (CoN4O2 chromophore) The shape of the coordination polyhedron of the cobalt(II) ion is that of a slightly distorted octahedral.

Adres publiczny

https://doi.org/10.1016/S1387-7003(03)00010-8

Strona internetowa wydawcy

http://www.elsevier.com

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