Wydział Chemii

Mirosław Karbowiak

A. Mech

Janusz Drożdżyński

Witold Ryba-Romanowski

M. F. Reid

2005

Journal of Physical Chemistry B

109

155-166

10.1021/jp047047h

Naukowa

Angielski

Artykuł

Low-temperature emission and polarized absorption spectra have been recorded for U(3+) ions diluted in Cs(3)Lu(2)Cl(9) and Cs(3)Y(2)I(9) host crystals. The experimental crystal-field levels were fitted to 13 parameters of a semiempirical Hamiltonian representing the combined atomic, one-electron crystal field (CF) as well as two-particle correlation crystal-field (CCF) operators. The red shift of the first f-d transitions from approximately 14,800 cm(-1) in the spectrum of U(3+):Cs(3)Lu(2)Cl(9) to as low as 11,790 cm(-1) in that of U(3+):Cs(3)Y(2)I(9) has been attributed to an increase in the covalence of the U(3+)-X(-) bonds. Comparison of the differences in the Coulomb repulsion strength between U(3+) and Er(3+) ions in Cs(3)Lu(2)Cl(9) and Cs(3)Y(2)I(9) crystals suggests that the 5f electrons of U(3+) ions are more 3d-like than 4f. The CF splitting of the (2)H(9/2) and (4)F(5/2) multiplets is unexpectedly larger for U(3+):Cs(3)Y(2)I(9) than for U(3+):Cs(3)Lu(2)Cl(9), which may be viewed as a result of the proximity of f-d states. For a correct description of the energy level structure of the (2)H(9/)(2) and (4)F(5/2) multiplets, the inclusion of CCF terms in the parametric Hamiltonian has proved to be essential. The larger f-f transition intensities for U(3+):Cs(3)Y(2)I(9) were also considered to be a consequence of the red shift of the first f-d states. The inadequacy in determination of the minor atomic parameters (other than parameters for Coulomb and spin-orbit interactions) and the insufficient inclusion of the influence of excited configuration in the applied CF Hamiltonian are assumed to be the main deficiencies preventing a better agreement between the experimental and calculated energies of CF levels.

https://doi.org/10.1021/jp047047h

https://www.acs.org/content/acs/en.html