Repozytorium

Redetermination of tetraphenylarsonium trans-aquatetrachlorooxorhenate(V) at 100 K.

Autorzy

Miłosz Siczek

Tadeusz Lis

Rok wydania

2006

Czasopismo

Acta Crystallographica Section E: Structure Reports Online

Numer woluminu

E62

Strony

m358-m359

DOI

10.1107/S1600536806001747

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

The crystal structure of the title compound, (C24H2OAs)[ ReCl4O(H2O)], has been re-examined at 100 K. The complex contains distorted octahedral [ReOCl4( H2O)](-) anions, with the Re atom and disordered aqua ligand located on a fourfold axis, and [Ph4As](+) cations with the As atom located on a fourfold inversion axis. In the anion, the terminal Re=O bond, 1.662 (2) angstrom S, is trans to the aqua ligand and the Re (OH2) and Re-Cl distances are 2.325 (3) and 2.3479 ( 5) angstrom S, respectively.

Adres publiczny

https://doi.org/10.1107/S1600536806001747

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