Wydział Chemii

G. J. Sopasis

Angelos B. Canaj

Aggelos Philippidis

Miłosz Siczek

Tadeusz Lis

J. R. O’Brien

M. M. Antonakis

S. A. Pergantis

Constantinos J. Milios

2012

Inorganic Chemistry

51

5911-5918

10.1021/ic300538q

Naukowa

Angielski

Artykuł

Employment of the artificial amino acid 2-amino-isobutyric acid, aibH, in Cu(II) and Cu(II)/Ln(III) chemistry led to the isolation and characterization of 12 new heterometallic heptanuclear [Cu(6)Ln(aib)(6)(OH)(3)(OAc)(3)(NO(3))(3)] complexes consisting of trivalent lanthanide centers within a hexanuclear copper trigonal prism (aibH = 2-amino-butyric acid; Ln = Ce (1), Pr (2), Nd (3), Sm (4), Eu (5), Gd (6), Tb (7), Dy (8), Ho (9), Er (10), Tm (11), and Yb (12)). Direct curent magnetic susceptibility studies have been carried out in the 5-300 K range for all complexes, revealing the different nature of the magnetic interactions between the 3d-4f metallic pairs: dominant antiferromagnetic interactions for the majority of the pairs and dominant ferromagnetic interactions for when the lanthanide center is Gd(III) and Dy(III). Furthermore, alternating current magnetic susceptibility studies reveal the possibility of single-molecule magnetism behavior for complexes 7 and 8. Finally, complexes 2, 5-8, 10, and 12 were analyzed using positive ion electrospray mass spectrometry (ES-MS), establishing the structural integrity of the heterometallic heptanuclear cage structure in acetonitrile.

http://dx.doi.org/10.1021/ic300538q

https://www.acs.org/content/acs/en.html