Repozytorium

Design of shape-palladium nanoparticles anchored on titanium(IV) metal-organic framework: highly active catalysts for reduction of p-nitrophenol in water.

Autorzy

Adam W. Augustyniak

Masaaki Sadakiyo

Jorge A. R. Navarro

Anna M. Trzeciak

Rok wydania

2018

Czasopismo

ChemistrySelect

Numer woluminu

3

Strony

7934-7939

DOI

10.1002/slct.201801644

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

The three‐dimensional microporous Ti‐based MOF material MIL‐125‐NH2 (MIL: Material of Institut Lavoisier) was successfully used as a support for palladium nanoparticles designed as catalysts for p‐nitrophenol hydrogenation. According to the mild and green synthetic approach, two catalysts of different nanoparticle morphology and different catalytic activity were obtained. Enhanced catalytic activity was found for a catalyst prepared using KBr as a capping agent, while Pd NPs of undefined shape synthesized without KBr were less active.

Słowa kluczowe

capping agent, hydrogenation, MOFs, palladium, shapes

Adres publiczny

https://doi.org/10.1002/slct.201801644

Strona internetowa wydawcy

onlinelibrary.wiley.com

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