Repozytorium
Wyszukaj
Kolekcje
Inne
Photophysical and theoretical studies of structure and spectroscopic behaviour of axially substituted Yb(III) mono-phthalocyanines in different media.
Autorzy
Rok wydania
2015
Czasopismo
Journal of Photochemistry and Photobiology A-Chemistry
Numer woluminu
309
Strony
65-71
DOI
10.1016/j.jphotochem.2015.04.022
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Lanthanide complexes with phthalocyanines (Pc) and porphyrins belong to the group of most investigated compounds because of their unique luminescence properties and variety of applications. The special interest is directed to medical applications, mainly in photodynamic therapy. This paper is devoted to photophysical studies of acetato- and chloro-ytterbium monophthalocyanine complexes in the solid state, solutions, silica matrices and PMMA polymer which can design their applicability. The structures, IR, and Raman spectra were calculated applying Hartree–Fock and density functional theory methods and further correlated with experimental findings. The theory reproduces reasonably spectroscopic frequencies of YbPcOAc2DMSO chelate. Two molecules of DMSO with somewhat different spectroscopic behaviour were found to exist in this complex.
The mechanism of the effect of conformation changes, steric obstacles, extra-coordination of solvent molecules and molecule immobilization in polymer and inorganic matrices on lanthanide and phthalocyanine emission spectra was discussed. Attention was paid to the radiative and non-radiative processes, intramolecular energy transfer and the role of charge-transfer state in this process, electron–phonon coupling, multiion cooperative interactions, non-linear proceses and dynamics in excited states. The role of solvent molecule exchange dynamic in possible interaction of Yb(III) complexes with biological systems was also analysed.
Słowa kluczowe
Ytterbium, Monophthalocyanine, DFT modelling method, Ab initio HF calculation, Spectroscopic properties, Sol–gel systems, Polymers co-doped by Yb-complexes
Adres publiczny
http://dx.doi.org/10.1016/j.jphotochem.2015.04.022
Strona internetowa wydawcy
Podobne publikacje
Photophysical properties and ab initio HF and DFT calculations of the structure and spectroscopy of axially chloro substituted Yb(III) monophthalocyanines in different systems.
Gerasymchuk Yuriy S., Guzik Małgorzata, Lisiecki Radosław, Sobczyk Marcin, Jański Jerzy, Koll Aleksander, Boulon Georges, Legendziewicz Janina
Comparison of ab initio HF and DFT calculations of the structure and spectroscopy of two dimeric systems of chloro Yb(III) mono-phthalocyanine in polymeric lattice.
Gerasymchuk Yuriy S., Guzik Małgorzata, Jański Jerzy, Boulon Georges, Legendziewicz Janina
Axially substituted ytterbium(III) monophthalocyanine - synthesis and their spectral properties in solid state, solution and in monolithic silica blocks.
Gerasymchuk Yuriy S., Tomachynski L. A., Tretyakova I. N., Hanuza Jerzy, Legendziewicz Janina