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Ferroiki, piezoelektryki i półprzewodniki w grupie kryształów hybryd organiczno-nieorganicznych = Ferroics, piezoelectrics and semiconductors in the group of organic-inorganic hybrid crystals
Autorzy
Rok wydania
2026
Czasopismo
Numer woluminu
80
Strony
531-551
DOI
10.53584/wiadchem.2026.02.21
Kolekcja
Język
Polski
Typ publikacji
Artykuł
This article presents the most representative research results on organicinorganic hybrids obtained by the Ferroic and Semiconductor Research Group at the Faculty of Chemistry, University of Wrocław. Particular attention is paid to the correlation between the properties of the characterized hybrids and their crystal structure. The most important properties of the following crystals are presented: (i) organic-inorganic hybrids from the haloantimonate(III) and halobismuthate(III) families, with the general formula RaMbX3b+a (where R represents organic cations, M = Sb(III) or Bi(III) and X = Cl, Br, I), (ii) cyanide coordination polymers with a double perovskite structure, and (iii) crystals based on alanine derivatives. Several complementary methods were used to study the physicochemical properties and structural mechanisms of phase transitions in the presented materials. An attempt was made to propose possible methods for technical applications of the presented materials.
Słowa kluczowe
ferroelectrics, ferroelastics, piezoelectricity, PFM, electric properties, phase transitions, semiconductors
ferroelektryk, ferroelastyk, piezoelektryczność, PFM, właściwości elektryczne, przemiany fazowe, półprzewodniki
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