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Inne
Structure and phase transitions in tetramethylammonium pentachloroindate(III) crystals.
Autorzy
Rok wydania
1999
Czasopismo
Journal of Molecular Structure
Numer woluminu
511-512
Strony
345-354
DOI
10.1016/S0022-2860(99)00177-5
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Differential scanning calorimetry, dielectric, thermal expansion and X-ray diffraction studies on [N(CH3)4]8[In(HOEt)Cl5]3[In(H2O)Cl5] are reported. The crystal reveals a complex sequence of phase transitions of first-order type. The values of the transitions entropies suggest the “order–disorder” character of the phase transitions. The reorientational motions of the tetramethylammonium cations are expected to contribute to the mechanism of phase transitions in the tetramethylammonium salts studied.
Słowa kluczowe
Phase transitions, Tetramethylammonium pentachloroindate(III), Differential scanning calorimetry, Dilatometric measurements
Adres publiczny
https://doi.org/10.1016/S0022-2860(99)00177-5
Strona internetowa wydawcy
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