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Synthesis of homoleptic barium alkoxides and aryloxides and their reactions with Al.(CH3)3: a convenient route to heterometallic species.
Autorzy
Rok wydania
2005
Czasopismo
Numer woluminu
44
Strony
5194-5196
DOI
10.1021/ic0503129
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Reactions of metallic Ba with benzofuranol (dbbfoH) or diethylene glycol give homoleptic and homonuclear complexes Ba(dbbfo)2(dbbfoH)2·3dbbfoH and Ba{O(CH2CH2O)2}{O(CH2CH2OH)2}2 (60−89%). Both compounds and formerly described Ba{O(CH2CH2O)2Me}2 react with Al(CH3)3 to yield trinuclear heterobimetallic low-coordinated barium compounds with structure and geometry depending on the reaction stoichiometry and crystallization procedure.
Słowa kluczowe
Alcohols, Metals, Ligands, Crystal structure, Barium
Adres publiczny
https://doi.org/10.1021/ic0503129
Strona internetowa wydawcy
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