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Inne
1,4-Di(1,2,3-triazol-1-yl)butane as building block for the preparation of the iron(II) spin-crossover 2D coordination polymer.
Autorzy
Rok wydania
2005
Czasopismo
Numer woluminu
44
Strony
4463-4465
DOI
10.1021/ic050449z
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The novel bidentate ligand 1,4-di(1,2,3-triazol-1-yl)butane (bbtr) reacts with Fe(ClO4)2·6H2O to form the 2D coordination polymer with (3,6) network topology. The {[Fe(bbtr)3](ClO4)2}∞ represents an example of spin-crossover material based on 1,2,3-triazole as donor group, and displays an abrupt spin transition accompanied by a thermal hysteresis loop (T1/2↓ = 101 K and T1/2↑ = 109 K).
Słowa kluczowe
Coordination polymers, Ligands, Layers, Crystal structure, Quantum mechanics
Adres publiczny
https://doi.org/10.1021/ic050449z
Strona internetowa wydawcy
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