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Enantiomeric enrichment of a nonracemic conglomerate of a chiral oxo-rhenium(V) complex.
Autorzy
Rok wydania
2003
Czasopismo
Numer woluminu
27
Strony
1687-1689
DOI
10.1039/B308170B
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The enantiomer being in excess was readily recovered from a nonracemic conglomerate of chiral cis-[ReOCl2{OCMe2CMe2OP(OCMe2CMe2O)}py] by means of a difference in solubility between the enantiomer and the racemate; subsequently the solubility diagram and the specific optical rotation [α]589 = +1345 (±30 max. absolute error; c = 0.05 g per 100 cm3 in MeCN) for the pure enantiomer of the absolute configuration C was also determined.
Adres publiczny
https://doi.org/10.1039/B308170B
Strona internetowa wydawcy
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